MSDS SHEET - 1250 IIMAK (SPECIALTY INKS) ALL COLORS

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: 1250 Ink

SYNONYMS: Mark II Stamp Pad Ink

COLORS: Black, Blue, Red, Green, Brown and all other dye based colors

MANUFACTURER: Specialty Ink Company, Inc.

ADDRESS: 20 Dunton Avenue

Deer Park, NY 11729

EMERGENCY PHONE: 800-688-4005 - VEOLIA

OTHER CALLS: 631-586-3666

FAX PHONE: 631-586-3666

PREPARED BY: Keith Werwa

SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient CAS NO. % VOL SARA 313 Reportable Exposure Limit Exposure Limit

ACGIH-TLV OSHA PEL

Ethyl Alcohol 64-17-5 18 1000 ppm 1000 ppm

Methyl Cellosolve 109-86-4 37 Yes 5 ppm 25 ppm

Diacetone Alcohol 123-42-2 25 50 ppm 50 ppm

SECTION 3: HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW: Do not get in eyes, on skin or clothing. Do not breathe vapor or mist. Keep container closed. Use only with

adequate ventilation. Wash thoroughly after handling.

ROUTES OF ENTRY: Dermal contact. Eye contact. Inhalation. Ingestion.

POTENTIAL ACCUTE HEALTH EFFECTS

EYES: Irritation to eyes

SKIN: Irritation to skin

INGESTION: May cause nausea and or vomitting

INHALATION: May be toxic by inhalation. Irritation to the respiratory system.

SECTION 4: FIRST AID MEASURES

EYES: Affected individual should remove contact lens, if present. In case of contact with eyes, rinse immediately with plenty of water or

saline solution. Get medical attention if irritation occurs.

SKIN: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.

Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation occurs.

INGESTION: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious

person. Get medical attention immediately

INHALATION: If inhaled, remove to fresh air. Get medical attention if symptoms appear. If exposed person is not breathing, give artificial

respiration or oxygen applied by trained personnel.

SECTION 5: FIRE-FIGHTING MEASURES

FLAMMABLE LIMITS IN AIR, UPPER: 15.1

(% BY VOLUME) LOWER: 2.8

FLASH POINT: 102 F

METHOD USED: Closed cup

AUTOIGNITION TEMPERATURE: 545 F

HMIS HAZARD CLASSIFICATION

HEALTH: 2 FLAMMABILITY: 2 REACTIVITY: 0

PROTECTION: B

EXTINGUISHING MEDIA: Carbon dioxide. Dry chemical. Alcohol Foam. Water spray.

SPECIAL FIRE FIGHTING PROCEDURES: Firefighters should wear appropriate protective equipment and self contained breathing

apparatus (SCBA) with a full facepiece operated in positive pressure mode.

SECTION 5 NOTES: Avoid heat, sparks and open flame. Slightly flammable to flammable in presence of heat. Use an extinguishing agent

suitable for surrounding fires .

SECTION 6: ACCIDENTAL RELEASE MEASURES

ACCIDENTAL RELEASE MEASURES: Keep unnecessary personnel away. Use suitable protective equipment (Section 8). Remove sources

of ignition. Ventilate.

ENVIRONMENTAL PRECAUTIONS: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

METHODS FOR CLEANING UP:

Small spill and leak: Absorb with an inert material and place in an appropriate waste disposal container.

Large spill and leak: Contain and cover spill with an absorbent material. Collect and dispose in chemical waste drum. Use appropriate

containment to avoid environmental contamination. Place spilled material in an appropriate container for disposal.

SECTION 7: HANDLING AND STORAGE

HANDLING: Do not ingest. Do not get in eyes, on skin or on clothing. Keep container closed. Use only with adequate ventilation. Do not

breathe vapor or mist. Wash thoroughly after handling.

STORAGE: Keep container tightly closed. Keep container in a cool, well ventilated area.

STORAGE TEMPERATURE: 40-80 F

SHELF LIFE: 12 months from date of manufacture

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below

their respective occupational exposure limits. Ensure that eyewash stations and safety showers are proximal to the work-station location

PERSONAL PROTECTION:

RESPIRATORY PROTECTION: Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk

assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the

product and the safe working limits of the selected respirator.

EYE PROTECTION: Safety eyewear complying with an approved standard should be use when a risk assessment indicates this is necessary

to avoid exposure to liquid splashes, mists or dusts.

SKIN PROTECTION: Personal protective equipment for the body should be selected based on the task being performed and the risks

involved and should be approved by a specialist before handling this product.

PERSONAL PROTECTION IN CASE OF LARGE SPILL: Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not

be sufficient; consult a specialist BEFORE handling this product.

EXPOSURE GUIDELINES: See section 2

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE AND APPEARANCE: Liquid

ODOR: Mild

BOILING POINT: 256 F

MELTING POINT: -121 F

VAPOR PRESSURE (mmHg): 6

VAPOR DENSITY (AIR = 1): 2.62

SPECIFIC GRAVITY (H2O = 1): .9663

REACTIVITY IN WATER: None

SOLUBILITY IN WATER: Insoluble

SECTION 10: STABILITY AND REACTIVITY

STABILITY: Stable

CONDITIONS TO AVOID (STABILITY): Heat, sparks and open flame

INCOMPATIBILITY (MATERIAL TO AVOID): Strong oxidizing agents

HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Burning may produce CO and CO2

HAZARDOUS POLYMERIZATION: Will not occur

CONDITIONS TO AVOID (POLYMERIZATION): None

SECTION 11: TOXICOLOGICAL INFORMATION

METHYL CELLOSOLVE TOXICOLOGICAL INFORMATION:

Oral rat LD50: 4.9g/kg; inhalation rat LC50: 1500 ppm/7H; skin rabbit LD50: 2.4 g/kg.

DIACETONE ALCOHOL TOXICOLOGICAL INFORMATION: Oral rat LD50> 2000mg/kg; inhalation rat LC50 greater than near saturated

vapour concentration/ 1H, dermal rabbit LD50> 2000mg/kg

ETHYL ALCOHOL TOXICOLOGICAL INFORMATION: Oral rat LD50: 5800mg/kg; inhalation rat LC50: 16000 mg/l

Effects of chronic exposure: Skin and eye irritant. Injury to liver and kidneys.

SECTION 12: ECOLOGICAL INFORMATION

ENVIRONMENTAL TOXICITY

METHYL CELLOSOLVE:

Rainbow Trout (Salmo gairdneri) 96 hr. LC 50: = 16000 mg/l (nominal, static)

Bluegill 96 hr. LC 50: > 10000 mg/l (nominal, static)

Daphnia magna 24 hr LC50: > 10000 mg/l (nominal, static)

Brine Shrimp 24 hr LC50: > 10000 mg/l (nominal, static)

ETHYL ALCOHOL:

Fish:Fathead Minnow 96 hr. LC 50: 15300 mg/l

DIACETONE ALCOHOL:

Fish: LC/EC/IC50 > 100 mg/l

Aquatic Invertabrates: LC/EC/IC50 > 1000 mg/l

Aquatic Plants: LC/EC/IC50 > 1000 mg/l

SECTION 13: DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a

RCRA approved incinerator or disposed in a RCRA approved waste facility. Processing, use or contamination of this product may change the

waste management options. State and local disposal regulations may differ from federal disposal regulations. The user of this material has the

responsibility to dispose of container and unused contents in accordance with federal, state and local requirements.

SECTION 14: TRANSPORT INFORMATION

Refer to the following when using the below information and reshipping Inks and Thinners:

FLASH POINT 73 – 149 (HAZARDOUS BY GROUND IN 5 GALLON CONTAINER)

FLASHPOINT UNDER 73 (HAZARDOUS BY GROUND IN QUART OR LARGER CONTAINER)

AND FLASHPOINT 149 OR UNDER (HAZARDOUS BY AIR IN ANY UNIT OF MEASURE)

If size deems shipment hazardous, below markings are required

U.S. DEPARTMENT OF TRANSPORTATION (LAND, D.O.T.)

PROPER SHIPPING NAME: Printing Ink

HAZARD CLASS: 3

ID NUMBER: 1210

PACKING GROUP: III

WATER TRANSPORTATION (WATER, I.M.O.)

PROPER SHIPPING NAME: Printing Ink

HAZARD CLASS: 3

ID NUMBER: 1993

PACKING GROUP: III

AIR TRANSPORTATION (AIR, I.C.A.O.)

PROPER SHIPPING NAME: Printing Ink

HAZARD CLASS: 3

ID NUMBER: 1210

PACKING GROUP: III

SECTION 15: REGULATORY INFORMATION

U.S. FEDERAL REGULATIONS:

TSCA (TOXIC SUBSTANCE CONTROL ACT):

Ethyl Alcohol 64-17-5

Diacetone Alcohol 123-42-2

Methyl Cellosolve 111-77-3

311/312 HAZARD CATEGORIES: “Fire Hazard”, “Immediate Accute Health Hazard”, “Flammable Liquid”

U.S. FEDERAL REGULATIONS: Methyl Cellosolve is subject t otreporting requirements of SARA Title III, Section 313 of the

Emergency Planning Community Right to Know Act of 1986 and of 40 CFR 372. This product is in compliance with the EPA TSCA

inventory.

STATE REGULATIONS: California Safe Drinking Water Act (Prop 65) Listing: “WARNING: This product contains a chemical known to

the State of California to cause cancer and/or birth defects or other reproductive harm”

SECTION 16: OTHER INFORMATION

OTHER INFORMATION: The hazards listed on this MSDS are taken from the MSDS for each of the ingredients in this mixture. In

most cases, the maximum form of hazard is represented here. The TLV’s represent the conditions under which it is believed that

nearly all workers may be repeatedly exposed day after day without adverse effect . It must be remembered that each individual

reacts differently and some may experience discomfort while others do not. This MSDS is presented so that each individual will have

the information to deal safely with the use of this product. All material’s TSCA listed.

PREPARATION INFORMATION: Prepared by Specialty Ink Company, Inc.

DATE PREPARED: February 12, 2010

SUPERCEDES ALL PREVIOUSLY DATED MSDS

DISCLAIMER: As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly

disclaim all liability for any use of this material. Information contained heein is given in good faith and is believed to be true and

accurate. All statements or suggestions are made without any warranty, expressed or implied, regarding the accuracy of the

information, the hazards connected with the use of the material or results to be obtained from the use thereof.